Photophysical properties of di-Schiff bases: evaluating the synergistic effect of non-covalent interactions and alkyl spacers in enhanced emissions of solids

dc.contributor.authorSarkar, Madhushree
dc.date.accessioned2021-11-11T10:42:22Z
dc.date.available2021-11-11T10:42:22Z
dc.date.issued2016
dc.description.abstractPhotophysical properties of di-Schiff base compounds in the solution and solid states are explored. The di-Schiff bases with alkyl spacers (ethyl, butyl and hexyl) showed enhanced light emitting properties in the solid state, while quenching was observed for di-Schiff bases with a hydrazine spacer. The photoluminescence spectra and the crystal structure were compared with bis-pyridyl-ethyl-di-imine and bis-pyridyl-butyl-di-imine. The crystal structure analysis of the compounds rationalizes the observed results. The concentration dependent 1H-NMR and NOESY spectra showed the aggregation behaviour of the compounds.en_US
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra08582b
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3197
dc.language.isoenen_US
dc.publisherRSCen_US
dc.subjectChemistryen_US
dc.subjectPhotophysicalen_US
dc.subjectEmissions of solidsen_US
dc.titlePhotophysical properties of di-Schiff bases: evaluating the synergistic effect of non-covalent interactions and alkyl spacers in enhanced emissions of solidsen_US
dc.typeArticleen_US

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