Bond dissociation energies from equilibrium studies: Part 4.—The equilibrium Br2+ CH4⇌ HBr + CH3Br. Determination of D(CH3—Br) and ΔH °f(CH3Br, g)

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dc.contributor.authorFerguson, K. C.
dc.contributor.authorOkafo, E. N.
dc.contributor.authorWhittle, E.
dc.date.accessioned2025-02-11T07:19:37Z
dc.date.available2025-02-11T07:19:37Z
dc.date.issued1973
dc.description.abstractThe equilibrium Br2+ CH4⇌ HBr + CH3Br (2) has been studied in the range 347–477°C, with equilibrium being approached from both sides. Products additional to those required by eqn (2) were formed but it is believed that reliable values of the equilibrium constant K2 have been measured. Third-law calculations lead to ΔH°2=–26.4 ± 0.7 kJ mol–1 at 298 K from which ΔH°f(CH3Br, g)=–34.3 ± 0.8 kJ mol–1.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17497
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2)en_US
dc.subjectChemistryen_US
dc.subjectBond Dissociation Energyen_US
dc.subjectEquilibrium Studiesen_US
dc.subjectMethyl Bromideen_US
dc.subjectThermochemical Propertiesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleBond dissociation energies from equilibrium studies: Part 4.—The equilibrium Br2+ CH4⇌ HBr + CH3Br. Determination of D(CH3—Br) and ΔH °f(CH3Br, g)en_US
dc.typeArticleen_US

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