New Three-parameter Empirical Extension of the Arrhenius Equation suitable for the Precise Evaluation of Pseudo- thermodynamic Activation Parameters in Chemical Kinetics

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dc.contributor.authorAdams, Paul A.
dc.contributor.authorSheppard, John G.
dc.contributor.authorRidler, Gweneth M.
dc.contributor.authorRidler, Philip F.
dc.date.accessioned2025-04-12T04:28:30Z
dc.date.available2025-04-12T04:28:30Z
dc.date.issued1978
dc.description.abstractAn empirical extension of the logarithmic form of the classical Arrhenius equation is written as a simple three-parameter equation which fits precise experimental data on the variation of rate-constant with temperature better than any three-parameter extension of the Arrhenius equation yet proposed. The proposed equation has been compared with the three and four parameter equations of Hyne and Robertson for a series of sets of rate-constant against temperature data on solvolysis systems. The equation proposed here is simpler to apply, and provides at least as good a statistical fit to the data as does the three-parameter equation of Hyne and Robertson.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18649
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06)en_US
dc.subjectChemistryen_US
dc.subjectArrhenius equationen_US
dc.subjectChemical kineticsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleNew Three-parameter Empirical Extension of the Arrhenius Equation suitable for the Precise Evaluation of Pseudo- thermodynamic Activation Parameters in Chemical Kineticsen_US
dc.typeArticleen_US

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