Department of Mechanical engineering
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Item Co-deposited Zn-Cu/Gr nanocomposite: Corrosion behaviour and in-vitro cytotoxicity assessment(Taylor & Francis, 2021-04) Belgamwar, Sachin U.; Rathore, Jitendra S.Zn-Cu alloys have been considered as potential candidates for bioimplant applications due to their moderate corrosion rate and admirable mechanical properties with non-toxic nature to the human body. However, with the incorporation of advanced reinforcements, such as carbon allotropes, the properties and applicability of a Zn-Cu alloy matrix can be further enhanced. In this research, graphene (Gr) nanoplatelets reinforced Zn-Cu/Gr nanocomposites were synthesised through a modified electro-codeposition method with different concentrations of Gr (25, 50 and 100 mg L−1) in the electrolyte bath. The prepared powder samples were compacted and sintered to form pellets. The pellets were tested for mechanical and in-vitro corrosion. The obtained micro-hardness, compressive yield strength (CYS) and ultimate compressive strength (UCS) of Zn-Cu/Gr (100 mg L−1) nanocomposite are 151 HV, 340 MPs and 362 MPa with increments of 84.1%, 118% and 70.7% compared to pure Zn-Cu alloy, respectively. The reduced wear rates and friction coefficients of Zn-Cu/Gr nanocomposites are attributed to crystallite size refinement and Gr content. The electrochemical corrosion rate is reduced by 66.6% from 33 × 10−3 mm year−1 for pure Zn-Cu alloy to 11 × 10−3 mm year−1 for Zn-Cu/Gr (100 mg L−1) nanocomposites, owing to Gr barrier protection. The in-vitro cytotoxicity assessment reveals that the prepared Zn-Cu/Gr nanocomposite is non-toxic for Gr concentration up to 50 mg L−1 in the electrolyte bath. The results show that a non-toxic Zn-Cu/Gr nanocomposite with outstanding tribo-mechanical and anti-corrosion properties can be synthesised by the proposed method.Item Electro-codeposited γ-Zn-Ni/Gr composite coatings: Effect of graphene concentrations in the electrolyte bath on tribo-mechanical, anti-corrosion and anti-bacterial properties(Taylor & Francis, 2021-10) Jha, Prabhat Nath; Rathore, Jitendra S.; Belgamwar, Sachin U.In this paper, low-cost and industrially scalable γ-Zn-Ni/Gr composite coatings were electro-codeposited from an acid-sulphate based electrolyte bath. The microstructure, morphology, composition, microhardness, wear performance, corrosion resistance and anti-bacterial properties of the composite coatings were investigated in detail and compared with a Zn-Ni alloy coating. The XRD diffraction peaks of prepared coatings confirm the presence of the γ phase of the Zn-Ni alloy. Results suggested that the addition of Gr effectively reduced the crystallite size and altered the morphology. As a result, the microhardness, wear performance and corrosion resistance were improved significantly. The γ-Zn-Ni/Gr composite coating prepared with 100 mg L−1 of Gr addition in the electrolyte bath displayed the highest microhardness of 243 HV and the lowest coefficient of friction of 0.32. The anti-bacterial activity tests confirmed that the γ-Zn-Ni/Gr composite coating (from the 100 mg L−1 bath) has the highest anti-bacterial activity against both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus).Item Electro-codeposition and properties of Cu–Ni-MWCNTs composite coatings(Taylor & Francis, 2021-02) Belgamwar, Sachin U.; Rathore, Jitendra S.In this work, multi-walled carbon nanotubes reinforced Cu–Ni matrix (Cu–Ni-MWCNTs) composite coatings were produced using the electro-codeposition method by adding different concentrations of MWCNTs (0.05, 0.1 and 0.15 g L−1) to the Cu–Ni plating bath. To achieve effective dispersion of the MWCNTs, the plating solution was stirred using an ultrasonicator (20 kHz and 500 W) for 120 min. Cu–Ni-MWCNTs composite coatings were characterised by scanning electron microscopy and X-ray diffraction to study the surface morphology and microstructure of the coatings. In addition, the effects of MWCNTs on the microhardness, wear resistance and electrical conductivity of the coating were investigated by microhardness tester, pin on disk wear tester and four-point probe system respectively. All Cu–Ni-MWCNTs composite coatings showed enhanced microhardness and wear performance as compared to the Cu–Ni coating. The Cu–Ni-MWCNT (0.15 g L−1) composite coating exhibited maximum microhardness of 438 HV and minimum wear loss of 0.9 mg among all the coatings, in the same pin-on-disk test conditions, which is attributed to the combined effect of microstructural refinement, higher content of MWCNTs and superior properties of MWCNTs. Electrical studies reveal that MWCNTs play a vital role in increasing electrical conductivity by 1.21 times of magnitude.