Kinetics of the Thermal Isomerisation of Hexamethyldisilane
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Date
1974
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Publisher
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)
Abstract
A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and
780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on
the thermolysis of hexamethyldisilane. The isomerisation is a radical chain reaction of three halves
order, with rate constants given by Xr/cmJ moH s-' = iol6-6s±o-7O exp[— (251 ± 8)/2?T] (activation
energy in kJ mol-1).
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Keywords
Chemistry, Kinetics, Hexamethyldisilane, Journal of the Chemical Society : Faraday Transaction - I