Nuclear Magnetic Resonance Studies of Preferential Solvation: Part 2.—Thermodynamic Treatment and application to Methanol + Water Solvents
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Date
1973
Journal Title
Journal ISSN
Volume Title
Publisher
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5)
Abstract
Prom a detailed consideration oi the thermodynamics of preferential solvation of ions in a binary solvent mixture, making reasonable assumptions about the variation of chemical potential of the variously solvated ions with solvent composition, it is shown how the variation of the free energy of transfer of a salt from water to mixed aqueous solvents derived from e.m.f. measurements can be related to spectroscopic information.
Description
Keywords
Chemistry, Magnetic Resonance Studies, Methanol, Water Solvents, Journal of the Chemical Society : Faraday Transaction - I