Photochemistry of 1,3-DichIoro-tetrafluoroacetone: Part 2.—The Triplet State
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Date
1972
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Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2)
Abstract
Quantum yields of S1→ T1 intersystem crossing in 1,3-dichloro-tetrafluoroacetone have been measured using the technique of biacetyl sensitization. The vibrationally-relaxed singlet state of the molecule intersystem crosses to a dissociative triplet with quantum yield 0.92. Vibrationally-excited singlet-state molecules do not intersystem cross, but may dissociate in two ways.
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Keywords
Chemistry, Photochemistry, 1,3-DichIoro-tetrafluoroacetone, Triplet State, Journal of the Chemical Society : Faraday Transaction - I