Facile β-Alkyl and β-Hydride Elimination in the Nickel-Catalyzed Annulation of o-Iodophenyl Ketones and Aldehydes with Bicyclic Alkenes
| dc.contributor.author | Shukla, Paritosh | |
| dc.date.accessioned | 2021-11-11T10:54:03Z | |
| dc.date.available | 2021-11-11T10:54:03Z | |
| dc.date.issued | 2006-05-26 | |
| dc.description.abstract | o-Iodoaryl aldehydes react with bicyclic alkenes in the presence of NiBr2(dppe) and Zn powder in acetonitrile at 80 °C undergoing annulation to give polycyclic ketone derivatives. Surprisingly, o-iodoaryl alkyl ketones also react with bicyclic alkenes to form polycyclic ketones with structures the same as those from the corresponding o-iodoaryl aldehydes. | en_US |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ol061051p | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3291 | |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Hydrocarbons | en_US |
| dc.subject | Annulations | en_US |
| dc.subject | Reaction products | en_US |
| dc.title | Facile β-Alkyl and β-Hydride Elimination in the Nickel-Catalyzed Annulation of o-Iodophenyl Ketones and Aldehydes with Bicyclic Alkenes | en_US |
| dc.type | Article | en_US |
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