Self-reactions of Isopropylperoxy Radicals in the Gas Phase
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Date
1978
Journal Title
Journal ISSN
Volume Title
Publisher
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)
Abstract
The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± 0.03 and Eobs= 18.65 ± 0.50 kJ mol–1 have been determined over a temperature range 300–373 K. These values are compared with those obtained for the self-reactions of primary and tertiary alkylperoxyradicals, and the corresponding reactions in solution.
Description
Keywords
Chemistry, Isopropylperoxy radical, Journal of the Chemical Society : Faraday Transaction - I